Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


metal-organic compounds



bx2449 scheme

Acta Cryst. (2013). E69, m590    [ doi:10.1107/S1600536813026160 ]

[2,6-Di­fluoro-3-(pyridin-2-yl-[kappa]N)pyridin-4-yl-[kappa]C4](penta­ne-2,4-dionato-[kappa]2O,O')iridium(III)

K. Luo, C. Zhang, J. Jia and D. Luo

Abstract: The title compound, [Ir(C10H5F2N2)2(C5H7O2)], has a distorted octa­hedral coordination geometry around the IrIII atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-di­fluoro-3-(pyridin-2-yl-[kappa]N)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)°]. The mol­ecular structure is stabilized by weak C-H...O and C-H...F hydrogen-bond inter­actions. The crystal structure is stabilized by [pi]-[pi] stacking inter­actions (centroid-centroid distance = 3.951 Å).


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