Acta Cryst. (2013). E69, m590 [ doi:10.1107/S1600536813026160 ]
Abstract: The title compound, [Ir(C10H5F2N2)2(C5H7O2)], has a distorted octahedral coordination geometry around the IrIII atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-difluoro-3-(pyridin-2-yl-N)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)°]. The molecular structure is stabilized by weak C-HO and C-HF hydrogen-bond interactions. The crystal structure is stabilized by - stacking interactions (centroid-centroid distance = 3.951 Å).
CCDC reference: 962596
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