Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


metal-organic compounds



cv5429 scheme

Acta Cryst. (2013). E69, m619    [ doi:10.1107/S1600536813028687 ]

Poly[([mu]6-benzene-1,3,5-tri­carboxyl­ato-[kappa]6O1:O1':O3:O3':O5:O5')tris­(N,N-di­methyl­formamide-[kappa]O)tris­([mu]3-formato-[kappa]3O:O:O')trizinc(II)]

J. Sim, T. Kim and J. K. Yang

Abstract: The asymmetric unit of the title compound, [Zn3(HCO2)3(C9H3O6)(C3H7NO)3]n, contains one Zn ion, one formate ligand, one N,N-di­methyl­formamide (DMF) ligand and one-third of a benzene-1,3,5-tri­carboxyl­ate (btc) ligand situated on a crystallographic 3 axis. Each ZnII atom is coordinated by one O atom from a DMF ligand, two O atoms from two btc ligands and three O atoms from three formate ligands in a distorted octa­hedral geometry. The ZnII atoms are connected by the formate and btc ligands, forming hexanuclear cores, which are linked by btc ligands, constructing a two-dimensional layered network along the ab plane.


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