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Volume 69 
Part 11 
Pages m612-m613  
November 2013  

Received 4 September 2013
Accepted 15 October 2013
Online 19 October 2013

Key indicators
Single-crystal X-ray study
T = 183 K
Mean [sigma](C-C) = 0.008 Å
H completeness 29%
R = 0.036
wR = 0.099
Data-to-parameter ratio = 17.9
Details
Open access

Rubidium penta­aqua­(L-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) L-serine monosolvate deca­hydrate

aDepartment of Chemical Engineering, School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei-city, Tokyo, Japan,bChemical Resouces Laboratory, Tokyo Institute of Technology, 4259, Nagatsuta, Midori-ku, Yokohama-city, Kanagawa, Japan, and cDivision of Applied Chemistry, Institute of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei-city, Tokyo, Japan
Correspondence e-mail: j_iijima@cc.tuat.ac.jp

The Co2+ ion in the title compound, Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O, is coordinated by five water mol­ecules and one O-monodentate L-serine ligand in a slightly distorted octahedral geometry. The Rb+ ion is irregularly coordinated by nine O atoms. In the crystal, the [H6CoIIIMo6O24]3- polyanions are stacked along the b-axis direction, mediated by bridging Rb-O bonds. N-H...O and O-H...O hydrogen bonds are observed involving the L-serine mol­ecules.

Related literature

For background to polyoxidometallates (POMs), see: Hasenknopf et al. (2008[Hasenknopf, B., Micoine, K., Lacóte, E., Thorimbert, S., Malacria, M. & Thoubenot, R. (2008). Eur. J. Inorg. Chem. pp. 5001-5013.]); Du et al. (2013[Du, D. Y., Yan, L. K., Su, Z. M., Li, S. L., Lan, Y. Q. & Wang, E. B. (2013). Coord. Chem. Rev. 257, 702-717.]); Fang et al. (2005[Fang, X. K., Anderson, T. M. & Hill, C. L. (2005). Angew. Chem. Int. Ed. 44, 3540-3544.]); Kortz et al. (2002[Kortz, U., Savelieff, M. G., Ghalim, F. Y. A., Khali, L. M., Maalouf, S. A. & Sinno, D. I. (2002). Angew. Chem. Int. Ed. 41, 4070-4073.]); Sadakane et al. (2001[Sadakane, M., Dickman, M. H. & Pope, M. T. (2001). Inorg. Chem. 40, 2715-2719.]); Tan et al. (2007[Tan, H., Li, Y., Zhang, Z., Qin, C., Wang, X., Wang, E. & Su, Z. (2007). J. Am. Chem. Soc. 129, 10066-10067.]); Inoue & Yamase (1995[Inoue, M. & Yamase, T. (1995). Bull. Chem. Soc. Jpn, 38, 3055-3063.]). For C-O bond lengths in carboxyl­ates, see: Lide (2007[Lide, D. E. (2007). Handbook of Chemistry and Physics, 88th ed., pp. 7-8. Boca Raton: CRC Press.]). For bond-valence sums, see: Brown (1980[Brown, I. D. (1980). Structure and Bonding in Crystals, Vol. II, pp. 1-30. New York: Academic Press.]). For protonation of POMs, see: Perloff (1970[Perloff, A. (1970). Inorg. Chem. 9, 2228-2239.]); Honda et al. (2007[Honda, D., Ikegami, S., Inoue, T., Ozeki, T. & Yagasaki, A. (2007). Inorg. Chem. 46, 1464-1470.]); Yang et al. (2013[Yang, Y., Xu, L., Li, F. & Qu, X. (2013). Inorg. Chem. Commun. 33, 142-146.]). For chiral POMs constructed from an Anderson-type POM as a building block, see: An et al. (2008[An, H., Han, Z., Xu, T., Meng, C. & Wang, E. (2008). Inorg. Chem. Commun. 11, 914-917.]).

[Scheme 1]

Experimental

Crystal data
  • Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O

  • Mr = 1649.42

  • Orthorhombic, P 21 21 21

  • a = 10.8411 (5) Å

  • b = 11.5923 (4) Å

  • c = 34.8078 (12) Å

  • V = 4374.4 (3) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 3.63 mm-1

  • T = 183 K

  • 0.41 × 0.36 × 0.19 mm

Data collection
  • Rigaku R-AXIS RAPID diffractometer

  • Absorption correction: numerical (NUMABS; Rigaku, 1999[Rigaku (1999). NUMABS. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.123, Tmax = 0.500

  • 70065 measured reflections

  • 10010 independent reflections

  • 9728 reflections with F2 > 2[sigma](F2)

  • Rint = 0.062

Refinement
  • R[F2 > 2[sigma](F2)] = 0.036

  • wR(F2) = 0.099

  • S = 1.04

  • 10010 reflections

  • 559 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 3.61 e Å-3

  • [Delta][rho]min = -1.10 e Å-3

  • Absolute structure: Flack (1983[Flack, H. D. (1983). Acta Cryst. A39, 876-881.]), 4426 Friedel pairs

  • Absolute structure parameter: 0.025 (7)

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O27-H4...O41 0.84 2.24 2.859 (6) 131
O27-H4...N1 0.84 2.62 2.940 (6) 104
O30-H11...O42i 0.84 2.24 2.928 (6) 139
N1-H5...O2 0.91 2.11 2.944 (6) 151
N1-H6...O39i 0.91 2.14 3.041 (6) 170
N1-H7...O17ii 0.91 2.09 2.905 (6) 149
N2-H13...O43 0.91 2.11 3.013 (7) 170
N2-H12...O8iii 0.91 2.31 2.912 (6) 123
N2-H14...O13iv 0.91 1.93 2.827 (6) 167
Symmetry codes: (i) [x+{\script{1\over 2}}, -y+{\script{1\over 2}}, -z]; (ii) [-x+2, y-{\script{1\over 2}}, -z+{\script{1\over 2}}]; (iii) [-x+1, y-{\script{1\over 2}}, -z+{\script{1\over 2}}]; (iv) x, y-1, z.

Data collection: RAPID-AUTO (Rigaku/MSC, 2002[Rigaku/MSC (2002). RAPID-AUTO. Rigaku/MSC, The Woodlands, Texas, USA.]); cell refinement: RAPID-AUTO; data reduction: RAPID-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: CrystalStructure (Rigaku, 2010[Rigaku (2010). CrystalStructure. Rigaku Corporation, Tokyo, Japan.]); software used to prepare material for publication: CrystalStructure.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HB7134 ).


References

An, H., Han, Z., Xu, T., Meng, C. & Wang, E. (2008). Inorg. Chem. Commun. 11, 914-917.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Brown, I. D. (1980). Structure and Bonding in Crystals, Vol. II, pp. 1-30. New York: Academic Press.
Du, D. Y., Yan, L. K., Su, Z. M., Li, S. L., Lan, Y. Q. & Wang, E. B. (2013). Coord. Chem. Rev. 257, 702-717.  [Web of Science] [CrossRef] [ChemPort]
Fang, X. K., Anderson, T. M. & Hill, C. L. (2005). Angew. Chem. Int. Ed. 44, 3540-3544.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Flack, H. D. (1983). Acta Cryst. A39, 876-881.  [CrossRef] [IUCr Journals]
Hasenknopf, B., Micoine, K., Lacóte, E., Thorimbert, S., Malacria, M. & Thoubenot, R. (2008). Eur. J. Inorg. Chem. pp. 5001-5013.  [Web of Science] [CrossRef]
Honda, D., Ikegami, S., Inoue, T., Ozeki, T. & Yagasaki, A. (2007). Inorg. Chem. 46, 1464-1470.  [Web of Science] [CSD] [CrossRef] [PubMed] [ChemPort]
Inoue, M. & Yamase, T. (1995). Bull. Chem. Soc. Jpn, 38, 3055-3063.  [CrossRef] [Web of Science]
Kortz, U., Savelieff, M. G., Ghalim, F. Y. A., Khali, L. M., Maalouf, S. A. & Sinno, D. I. (2002). Angew. Chem. Int. Ed. 41, 4070-4073.  [CrossRef] [ChemPort]
Lide, D. E. (2007). Handbook of Chemistry and Physics, 88th ed., pp. 7-8. Boca Raton: CRC Press.
Perloff, A. (1970). Inorg. Chem. 9, 2228-2239.  [CrossRef] [ChemPort] [Web of Science]
Rigaku (1999). NUMABS. Rigaku Corporation, Tokyo, Japan.
Rigaku (2010). CrystalStructure. Rigaku Corporation, Tokyo, Japan.
Rigaku/MSC (2002). RAPID-AUTO. Rigaku/MSC, The Woodlands, Texas, USA.
Sadakane, M., Dickman, M. H. & Pope, M. T. (2001). Inorg. Chem. 40, 2715-2719.  [Web of Science] [CrossRef] [PubMed] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Tan, H., Li, Y., Zhang, Z., Qin, C., Wang, X., Wang, E. & Su, Z. (2007). J. Am. Chem. Soc. 129, 10066-10067.  [Web of Science] [CrossRef] [PubMed] [ChemPort]
Yang, Y., Xu, L., Li, F. & Qu, X. (2013). Inorg. Chem. Commun. 33, 142-146.  [Web of Science] [CSD] [CrossRef] [ChemPort]


Acta Cryst (2013). E69, m612-m613   [ doi:10.1107/S1600536813028304 ]

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