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Volume 69 
Part 11 
Pages m595-m596  
November 2013  

Received 3 October 2013
Accepted 4 October 2013
Online 12 October 2013

Key indicators
Single-crystal X-ray study
T = 295 K
Mean [sigma](C-C) = 0.019 Å
R = 0.115
wR = 0.308
Data-to-parameter ratio = 34.4
Details
Open access

Tetra­quinolinium ditelluro(VI)octa­vanadate(V) octa­hydrate

aLaboratoire de chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia
Correspondence e-mail: samah.akriche@fsb.rnu.tn

In the title compound, (C9H8N)4[Te2V8O28]·8H2O, the com­plete heteropolyanion is generated by a crystallographic inversion centre. One of the two quniolinium ions forms an N-H...Op (p = polyoxidometallate) hydrogen bond and the other an N-H...Ow (w = water) hydrogen bond. The water mol­ecules further link the components by O-H...Op and O-H...Ow hydrogen bonds. A number of C-H...O inter­actions and aromatic [pi]-[pi] stacking inter­actions [shortest centroid-centroid separation = 3.541 (7) Å] are also observed. Together, these generate a three-dimensional network.

Related literature

For applications of polyoxidometallates, see: Fukuda & Yamase (1997[Fukuda, N. & Yamase, T. (1997). Biol. Pharm. Bull. 20, 927-930.]); Rajakumar et al. (2000[Rajakumar, V. D., Barbara, H. & Amanda, L. (2000). Cardiovasc. Drugs Ther. 14, 463-470.]); Folbergrova & Mares (1987[Folbergrova, J. & Mares, P. (1987). Neurochem. Res. 12, 537-540.]); Fantus et al. (1995[Fantus, I. G., Deragon, G., Lai, R. & Tang, S. (1995). Mol. Cell. Biochem. 153, 103-112.]). For bond-valence calculations, see: Brown & Altermatt (1985[Brown, I. D. & Altermatt, D. (1985). Acta Cryst. B41, 244-247.]). For geometrical features in related structures, see: Lee et al. (2008[Lee, U., Joo, H. C., Park, K. M., Mal, S. S., Kortz, U., Keita, B. & Nadjo, L. (2008). Angew. Chem. Int. 47, 793-796.]); Joo et al. (2011[Joo, H.-C., Park, K.-M. & Lee, U. (2011). Acta Cryst. E67, m1801-m1802.]); Strukan et al. (1997[Strukan, N., Cindric, M. & Kamenar, B. (1997). Polyhedron, 16, 629-634.]); Konaka et al. (2008[Konaka, S., Ozawa, Y. & Yagasaki, A. (2008). Inorg. Chem. Commun. 11, 1267-1269.], 2011[Konaka, S., Ozawa, Y., Shonaka, T., Watanabe, S. & Yagasaki, A. (2011). Inorg. Chem. 50, 6183-6188.]); Evans et al. (1966[Evans, H. T. (1966). Inorg. Chem. 5, 967-977.]); Hemissi et al. (2010[Hemissi, H., Rzaigui, M. & Al Othman, Z. A. (2010). Acta Cryst. E66, m186-m187.]).

[Scheme 1]

Experimental

Crystal data
  • (C9H8N)4[Te2V8O28]·8H2O

  • Mr = 1775.50

  • Triclinic, [P \overline 1]

  • a = 10.907 (3) Å

  • b = 11.302 (3) Å

  • c = 13.169 (2) Å

  • [alpha] = 106.45 (4)°

  • [beta] = 107.71 (4)°

  • [gamma] = 105.34 (4)°

  • V = 1369.4 (6) Å3

  • Z = 1

  • Ag K[alpha] radiation

  • [lambda] = 0.56087 Å

  • [mu] = 1.28 mm-1

  • T = 295 K

  • 0.19 × 0.15 × 0.09 mm

Data collection
  • Enraf-Nonius CAD-4 diffractometer

  • Absorption correction: analytical (Alcock, 1970[Alcock, N. W. (1970). Crystallogr. Comput. p. 271.]) Tmin = 0.561, Tmax = 0.725

  • 16455 measured reflections

  • 13245 independent reflections

  • 6549 reflections with I > 2[sigma](I)

  • Rint = 0.045

  • 2 standard reflections every 120 min intensity decay: 4%

Refinement
  • R[F2 > 2[sigma](F2)] = 0.115

  • wR(F2) = 0.308

  • S = 1.05

  • 13245 reflections

  • 385 parameters

  • 20 restraints

  • H atoms treated by a mixture of independent and constrained refinement

  • [Delta][rho]max = 3.11 e Å-3

  • [Delta][rho]min = -2.28 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O1W-H2W1...O2i 0.85 (1) 1.82 (1) 2.663 (8) 178 (1)
O1W-H1W1...O7 0.85 (1) 1.92 (2) 2.762 (9) 170 (4)
O2W-H1W2...O8ii 0.85 (1) 2.03 (2) 2.842 (10) 159 (4)
O2W-H2W2...O4Wiii 0.85 (1) 2.10 (1) 2.952 (14) 177 (1)
O3W-H2W3...O4W 0.84 (1) 1.91 (1) 2.754 (14) 177 (1)
O3W-H1W3...O6ii 0.85 (1) 1.83 (2) 2.665 (11) 166 (6)
O4W-H2W4...O1Wiv 0.85 (1) 2.41 (3) 2.826 (12) 111 (3)
O4W-H1W4...O2W 0.85 (1) 2.26 (5) 2.836 (17) 125 (5)
N1-H1...O1W 0.86 1.85 2.700 (11) 172
N2-H2...O14 0.86 1.88 2.740 (9) 175
C5-H5...O6ii 0.93 2.29 3.180 (13) 160
C6-H6...O13v 0.93 2.48 3.178 (14) 132
C7-H7...O1vi 0.93 2.56 3.350 (13) 143
C7-H7...O2Wvii 0.93 2.57 3.296 (14) 135
C10-H10...O9viii 0.93 2.51 3.275 (13) 140
C14-H14...O4ix 0.93 2.58 3.403 (14) 148
C17-H17...O5 0.93 2.60 3.411 (13) 146
Symmetry codes: (i) -x, -y, -z+1; (ii) x+1, y, z+1; (iii) -x+2, -y, -z+2; (iv) x+1, y, z; (v) -x+1, -y+1, -z+2; (vi) x, y-1, z; (vii) x-1, y, z; (viii) -x+1, -y+1, -z+1; (ix) -x+1, -y+2, -z+1.

Data collection: CAD-4 EXPRESS (Enraf-Nonius, 1994[Enraf-Nonius (1994). CAD-4 EXPRESS. Enraf-Nonius, Delft, The Netherlands.]); cell refinement: CAD-4 EXPRESS; data reduction: XCAD4 (Harms & Wocadlo, 1996[Harms, K. & Wocadlo, S. (1996). XCAD4. University of Marburg, Germany.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012[Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.]) and DIAMOND (Brandenburg & Putz, 2005[Brandenburg, K. & Putz, H. (2005). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: WinGX (Farrugia, 2012[Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HB7146 ).


References

Alcock, N. W. (1970). Crystallogr. Comput. p. 271.
Brandenburg, K. & Putz, H. (2005). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Brown, I. D. & Altermatt, D. (1985). Acta Cryst. B41, 244-247.  [CrossRef] [Web of Science] [IUCr Journals]
Enraf-Nonius (1994). CAD-4 EXPRESS. Enraf-Nonius, Delft, The Netherlands.
Evans, H. T. (1966). Inorg. Chem. 5, 967-977.  [CrossRef] [ChemPort] [Web of Science]
Fantus, I. G., Deragon, G., Lai, R. & Tang, S. (1995). Mol. Cell. Biochem. 153, 103-112.  [CrossRef] [ChemPort] [PubMed] [Web of Science]
Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Folbergrova, J. & Mares, P. (1987). Neurochem. Res. 12, 537-540.  [ChemPort] [PubMed] [Web of Science]
Fukuda, N. & Yamase, T. (1997). Biol. Pharm. Bull. 20, 927-930.  [CrossRef] [ChemPort] [PubMed]
Harms, K. & Wocadlo, S. (1996). XCAD4. University of Marburg, Germany.
Hemissi, H., Rzaigui, M. & Al Othman, Z. A. (2010). Acta Cryst. E66, m186-m187.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Joo, H.-C., Park, K.-M. & Lee, U. (2011). Acta Cryst. E67, m1801-m1802.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Konaka, S., Ozawa, Y., Shonaka, T., Watanabe, S. & Yagasaki, A. (2011). Inorg. Chem. 50, 6183-6188.  [Web of Science] [CSD] [CrossRef] [ChemPort] [PubMed]
Konaka, S., Ozawa, Y. & Yagasaki, A. (2008). Inorg. Chem. Commun. 11, 1267-1269.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Lee, U., Joo, H. C., Park, K. M., Mal, S. S., Kortz, U., Keita, B. & Nadjo, L. (2008). Angew. Chem. Int. 47, 793-796.  [ChemPort]
Rajakumar, V. D., Barbara, H. & Amanda, L. (2000). Cardiovasc. Drugs Ther. 14, 463-470.  [Web of Science] [PubMed]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Strukan, N., Cindric, M. & Kamenar, B. (1997). Polyhedron, 16, 629-634.  [CSD] [CrossRef] [ChemPort] [Web of Science]


Acta Cryst (2013). E69, m595-m596   [ doi:10.1107/S1600536813027347 ]

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