Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


metal-organic compounds



hy2637 scheme

Acta Cryst. (2013). E69, m573    [ doi:10.1107/S1600536813026524 ]

Poly[[[mu]-chlorido-[mu]-[2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol-[kappa]2N4:N4']-zinc] chloride dihydrate]

G.-H. Pan, J.-N. Tang, S.-H. Xu, Z.-J. Huang and B.-F. Mo

Abstract: The title compound, {[ZnCl(C13H12F2N6O)2]Cl·2H2O}n, is a two-dimensional coordination polymer. The ZnII atom is six-coordinated by four N atoms from four 2-(2,4-di­fluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-ol (HFlu) ligands and by two Cl atoms in a distorted octa­hedral geometry. Two Cl atoms bridge two ZnII atoms, forming a centrosymmetric dinuclear unit. The HFlu ligands connect the dinuclear units into a 44 net parallel to (001) when the dinuclear unit is considered as a node. O-H...O and O-H...Cl hydrogen bonds link the cationic layer, free chloride anions and lattice water mol­ecules. Intra­layer [pi]-[pi] inter­actions between the triazole rings are observed [centroid-centroid distance = 3.716 (6) Å].


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813026524/hy2637sup0.html ]
Supplementary materials


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster