Acta Cryst. (2013). E69, m607
[ doi:10.1107/S1600536813028195 ]
Abstract: In the title compound, [CoRu(C5H5)(C16H9)(C17H14P)2]PF6, the RuII atom is coordinated by a cyclopentadienyl ring in an 5-mode, one C atom from a 4,4'-diethynyl-1,1'-biphenyl ligand and two P atoms from a chelating 1,1'-bis(diphenylphosphanyl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C-HF hydrogen bonds link the complex cations and hexafluoridophosphate anions into a three-dimensional supramolecular structure.
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