Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m572    [ doi:10.1107/S1600536813026366 ]

Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-[kappa]2O,O')manganate(II) dihydrate

A. Elboulali, S. Akriche and M. Rzaigui

Abstract: The asymmetric unit of the title compound, (C8H12NO)2[Mn(H2P2O7)2(H2O)2]·2H2O, consists of half an MnII complex anion, a 2-meth­oxy­benyl­ammonium cation and a solvent water mol­ecule. The MnII complex anion lies across an inversion center, and has a slightly distorted octa­hedral coordination environment for the MnII ion, formed by two bidentate dihydrogendiphosphate ligands and two water mol­ecules. In the crystal, the components are linked by O-H...O and N-H...O hydrogen bonds, forming layers parallel to (100). An intra­molecular N-H...O hydrogen bond is also observed.

CCDC reference: 962829

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