[Open access]

[Contents scheme]

Acta Cryst. (2013). E69, m601
[ doi:10.1107/S1600536813027591 ]

Tris[4-bromo-2-(methyl­imino­meth­yl)phenolato-[kappa]2N,O]cobalt(III)

Q.-P. Huang, C.-L. Zhang, R.-X. Zhao, L. Yang and X.-F. Jiang

Abstract: In the title compound, [Co(C8H7BrNO)3], the CoIII ion is coordinated in a slightly distorted octa­hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl­imino­meth­yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol­ecules are linked by pairs of weak C-H...Br hydrogen bonds, forming inversion dimers.


Copyright © International Union of Crystallography
IUCr Webmaster