Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


metal-organic compounds



sj5353 scheme

Acta Cryst. (2013). E69, m575-m576    [ doi:10.1107/S1600536813026585 ]

Bis[[mu]-N-(pyridin-2-ylmeth­yl)pyridin-3-amine-[kappa]2N:N']disilver(I) bis­(perchlorate) dimethyl sulfoxide disolvate

S.-H. Moon and K.-M. Park

Abstract: In the binuclear title compound, [Ag2(C11H11N3)2](ClO4)2·2C2H6SO, the complex cation is centrosymmetric, with the unique AgI cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridine-2-ylmeth­yl)pyridine-3-amine ligands in a geometry slightly distorted from linear [N-Ag-N = 170.78 (9)°], resulting in the formation of a 16-membered cyclic dimer. The two pyridine rings coordinating to the AgI atom are almost perpendicular to each other [dihedral angle = 87.73 (10)°]. Inter­molecular Ag...O inter­actions [3.149 (3) and 2.686 (3) Å], N-H...O and C-H...O hydrogen bonds and C-H...[pi] inter­actions between the cyclic dimers and the anions or the solvent mol­ecules lead to the formation of a three-dimensional supra­molecular network.


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