Acta Cryst. (2013). E69, o1717-o1718
[ doi:10.1107/S1600536813029103 ]
Abstract: In the title compound, C15H13F3N2O2·H2O, the dihedral angle between the benzene and pyridine rings is 74.97 (1)°. The -CF3 group attached to the benzene ring is syn to the C=O bond in the adjacent side chain. In the crystal, molecules are linked to one another through the water molecules by strong N-HO, O-HO and O-HN hydrogen bonds, forming a ladder-type network. The benzamide molecules are also linked to one another through C-HF interactions, forming C(6) chains parallel to the b-axis direction. Aromatic - stacking interactions [centroid-centroid separations = 3.7150 (1) and 3.7857 (1) Å] between adjacent pairs of pyridine and benzene rings are also observed, resulting in a three-dimensional architecture are also observed.
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