Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


organic compounds



sj5360 scheme

Acta Cryst. (2013). E69, o1717-o1718    [ doi:10.1107/S1600536813029103 ]

4-Meth­oxy-N-(pyridin-4-ylmeth­yl)-3-(tri­fluoro­meth­yl)benzamide monohydrate

S. Sreenivasa, N. R. Mohan, V. Kumar, B. S. Palakshamurthy, D. B. Arunakumar and P. A. Suchetan

Abstract: In the title compound, C15H13F3N2O2·H2O, the dihedral angle between the benzene and pyridine rings is 74.97 (1)°. The -CF3 group attached to the benzene ring is syn to the C=O bond in the adjacent side chain. In the crystal, mol­ecules are linked to one another through the water mol­ecules by strong N-H...O, O-H...O and O-H...N hydrogen bonds, forming a ladder-type network. The benzamide mol­ecules are also linked to one another through C-H...F inter­actions, forming C(6) chains parallel to the b-axis direction. Aromatic [pi]-[pi] stacking inter­actions [centroid-centroid separations = 3.7150 (1) and 3.7857 (1) Å] between adjacent pairs of pyridine and benzene rings are also observed, resulting in a three-dimensional architecture are also observed.


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