Acta Cryst. (2013). E69, o1712 [ doi:10.1107/S1600536813028997 ]
Abstract: The title compound, C4H6ClNO3, crystallizes with two independent molecules (A and B) in the asymmetric unit. In each molecule, there are N-HO and N-HCl hydrogen bonds. Both molecules are relatively planar, with the mean plane of the acetamide [N-C(=O)C] group being inclined to the mean plane of the acetate group [C-C(=O)O] by 9.23 (13)° in molecule A and 6.23 (12)° in molecule B. In the crystal, adjacent molecules are linked by O-HO hydrogen bonds and weak C-HO contacts forming -A-A-A- and -B-B-B- parallel chains propagating along the a-axis direction.
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