Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m581-m582    [ doi:10.1107/S1600536813026901 ]

Tris(cyclo­hexyl­ammonium) cis-di­chlorido­bis­(oxalato-[kappa]2O1,O2)stann­ate(IV) chloride monohydrate

M. Sarr, W. Diallo, A. Diasse-Sarr, L. Plasseraud and H. Cattey

Abstract: The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclo­hexyl­ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol­ecule. The cyclo­hexyl­ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa­hedrally to the central SnIV atom. The cohesion of the mol­ecular entities is ensured by the formation of N-H...O, O-H...O, O-H...Cl and N-H...Cl inter­actions involving cations, anions and the lattice water mol­ecule, giving rise to a layer-like arrangement parallel to (010).

CCDC reference: 963857

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