Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m614-m615    [ doi:10.1107/S1600536813028067 ]

Bis[(di­methyl­phosphor­yl)methan­amin­ium] tetra­chlorido­palladate(II)

G. J. Reiss

Abstract: In the crystal structure of the title compound, (C3H11NOP)2[PdCl4], (di­methyl­phosphor­yl)methanaminium (dpmaH+) cations are connected head-to-tail by strong N-H...O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl4]2- counter-dianion is located about a center of inversion. The dications and the [PdCl4]2- dianions are connected by medium-strong N-H...Cl hydrogen bonds, forming zigzag chains parallel to [001]. Somewhat weaker N-H...Cl hydrogen bonds connect the chains into a three-dimensional network.

CCDC reference: 966191

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