Acta Cryst. (2013). E69, m626-m627 [ doi:10.1107/S1600536813029371 ]
Abstract: In the title compound, [Ti2(C16H14N2O2)2O2]·2CHCl3, the TiIV atom in the centrosymmetric complex has a distorted octahedral N2O4 coordination environment and is linked via two 2-oxido bridges into a dinuclear centrosymmetric complex, with a TiTi separation of 2.7794 (8) Å. In the salen (N,N'-ethylenebis(salicylimine)) ligand, the two salicylimine units make a dihedral angle of 45.31 (5)°. The complex molecules are stacked parallel to , forming channels in which the solvent chloroform molecules are located. C-HO hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing.
Hyper-Text Markup Language (HTML) file
MDL mol file (7.7 kbytes)
To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.
The download button will force most browsers to prompt for a file name to store the data on your hard disk.
Where possible, images are represented by thumbnails.
Copyright © International Union of Crystallography