Received 18 October 2013
aDepartment of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow 119991, Russian Federation, and bInstitute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow 119991, Russian Federation
Correspondence e-mail: firstname.lastname@example.org
In the title compound, [Ti2(C16H14N2O2)2O2]·2CHCl3, the TiIV atom in the centrosymmetric complex has a distorted octahedral N2O4 coordination environment and is linked via two 2-oxido bridges into a dinuclear centrosymmetric complex, with a TiTi separation of 2.7794 (8) Å. In the salen (N,N'-ethylenebis(salicylimine)) ligand, the two salicylimine units make a dihedral angle of 45.31 (5)°. The complex molecules are stacked parallel to , forming channels in which the solvent chloroform molecules are located. C-HO hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing.
For general background to the chemistry of titanium complexes based on salen-type ligands, see: Gupta & Sutar (2008); Tsuchimoto (2001). For our previous work on titanium(IV) complexes with polydentate N,O-chelating ligands, see: Zaitsev et al. (2006, 2008).
Data collection: APEX2 (Bruker, 2008); cell refinement: SAINT (Bruker, 2008); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: WM2780 ).
This work was partially supported by a grant from the President of the Russian Federation to support the research of young Russian scientists and doctors (MD-3634.2012.3).
Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Gupta, K. C. & Sutar, A. K. (2008). Coord. Chem. Rev. 252, 1420-1450.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Tsuchimoto, M. (2001). Bull. Chem. Soc. Jpn, 74, 2101-2105.
Zaitsev, K. V., Bermeshev, M. V., Samsonov, A. A., Oprunenko, J. F., Churakov, A. V., Howard, J. A. L., Karlov, S. S. & Zaitseva, G. S. (2008). New J. Chem. 32, 1415-1431.
Zaitsev, K. V., Karlov, S. S., Selina, A. A., Oprunenko, Yu. F., Churakov, A. V., Neumüller, B., Howard, J. A. K. & Zaitseva, G. S. (2006). Eur. J. Inorg. Chem. pp. 1987-1999.