Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


metal-organic compounds



xu5740 scheme

Acta Cryst. (2013). E69, m577-m578    [ doi:10.1107/S1600536813026287 ]

Poly[bis­(ethanol)([mu]4-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato)cadmium]

N. Ko and J. Kim

Abstract: In the title compound, [Cd(C8F4O4)(C2H5OH)2]n, the CdII cation sits on an inversion centre and is coordinated by six O atoms from four tetra­fluoro­benzene-1,4-di­carboxyl­ate anions and two ethanol mol­ecules in a distorted octa­hedral geometry. The anionic ligand is also located on an inversion centre, and connects four CdII cations, generating a two-dimensional polymeric layer parallel to the ab plane. Within the layer, the ethanol mol­ecule links F and O atoms of the nearest anionic ligands via O-H...O and O-H...F hydrogen bonds. The ethyl group of the ethanol mol­ecule is disordered over two positions with an occupancy ratio of 0.567 (10):0.433 (10).


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