Acta Cryst. (2013). E69, m577-m578 [ doi:10.1107/S1600536813026287 ]
Abstract: In the title compound, [Cd(C8F4O4)(C2H5OH)2]n, the CdII cation sits on an inversion centre and is coordinated by six O atoms from four tetrafluorobenzene-1,4-dicarboxylate anions and two ethanol molecules in a distorted octahedral geometry. The anionic ligand is also located on an inversion centre, and connects four CdII cations, generating a two-dimensional polymeric layer parallel to the ab plane. Within the layer, the ethanol molecule links F and O atoms of the nearest anionic ligands via O-HO and O-HF hydrogen bonds. The ethyl group of the ethanol molecule is disordered over two positions with an occupancy ratio of 0.567 (10):0.433 (10).
CCDC reference: 962922
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