Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


metal-organic compounds



xu5741 scheme

Acta Cryst. (2013). E69, m579-m580    [ doi:10.1107/S1600536813026640 ]

Poly[([mu]3-5-tert-butyl­benzene-1,3-di­carboxyl­ato)di­pyridine­cobalt(II)]

K. Noh and J. Kim

Abstract: In the title compound, [Co(C12H12O4)(C5H5N)2]n, the CoII cation is coordinated by four O atoms from three 5-tert-butyl­benzene-1,3-di­carboxyl­ate anions and two N atoms from pyridine mol­ecules in a distorted octa­hedral geometry. One carboxyl­ate group of the anionic ligand chelates a CoII cation while another carboxyl­ate group bridges two CoII cations, resulting in a polymeric layer parallel to (101). Weak C-H...O hydrogen bonds occur between adjacent polymeric layers. In the crystal, one of pyridine mol­ecules is equally disordered over two positions.


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