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Volume 69 
Part 11 
Page o1676  
November 2013  

Received 6 September 2013
Accepted 16 October 2013
Online 19 October 2013

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.002 Å
R = 0.041
wR = 0.140
Data-to-parameter ratio = 14.3
Details
Open access

(4-Hy­droxy-3,5-di­methyl­phen­yl)(phen­yl)methanone

aDepartment of Studies in Physics, Manasagangotri, University of Mysore, Mysore 570 006, India,bDepartment of Chemistry, Yuvaraja's College, University of Mysore, Mysore 570 005, India, and cDepartment of Physics, St Philomena's College, Mysore, India
Correspondence e-mail: mas@physics.uni-mysore.ac.in

In the mol­ecule of the title compound, C15H14O2, the dihedral angle between the benzene and phenyl rings is 61.27 (8)°. In the crystal, O-H...O and weak C-H...O hydrogen bonds link the mol­ecules into chains extending along the c-axis direction.

Related literature

For the biological activity of benzo­phenone derivatives, see: Naldoni et al. (2009[Naldoni, F. J., Claudino, A. L. R., Cruz, J. W., Chavasco, J. K., Faria e Silva, P. M., Veloso, M. P. & Dos Santos, M. H. (2009). J. Med. Food, 12, 403-407.]); Naveen et al. (2006[Naveen, S., Khanum, S. A., Devaiah, V. T., Shashikanth, S., Anandalwar, S. M. & Prasad, S. (2006). Anal. Sci. 22, 183-184.]); Selvi et al. (2003[Selvi, A. T., Joseph, G. S. & Jayaprakasha, G. K. (2003). Food Microbiol. 20, 455-460.]). For bond-length and angle data in a related structure, see: Mahendra et al. (2005[Mahendra, M., Khanum, S. A., Singh, A. K., Shashikanth, S., Doreswamy, B. H., Sridhar, M. A. & Shashidhara Prasad, J. (2005). Acta Cryst. E61, o2990-o2991.]).

[Scheme 1]

Experimental

Crystal data
  • C15H14O2

  • Mr = 226.26

  • Monoclinic, P 21 /c

  • a = 4.7741 (13) Å

  • b = 15.198 (4) Å

  • c = 17.274 (5) Å

  • [beta] = 95.275 (12)°

  • V = 1248.0 (6) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 0.08 mm-1

  • T = 293 K

  • 0.30 × 0.25 × 0.20 mm

Data collection
  • Bruker APEXII CCD area-detector diffractometer

  • 2238 measured reflections

  • 2238 independent reflections

  • 1777 reflections with I > 2[sigma](I)

Refinement
  • R[F2 > 2[sigma](F2)] = 0.041

  • wR(F2) = 0.140

  • S = 1.02

  • 2238 reflections

  • 157 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.15 e Å-3

  • [Delta][rho]min = -0.13 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O5-H5...O11i 0.82 2.03 2.7528 (17) 147
C13-H13...O5ii 0.93 2.55 3.301 (2) 138
Symmetry codes: (i) [x, -y+{\script{1\over 2}}, z+{\script{1\over 2}}]; (ii) [x-1, -y+{\script{1\over 2}}, z-{\script{1\over 2}}].

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]); software used to prepare material for publication: SHELXL97.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZS2279 ).


Acknowledgements

CSD would like to thank the University of Mysore for the award of an RFSMS fellowship under the head DV5/Physics/389/RFSMS/2009-2010/10.07.2012. The authors SAK and TP acknowledge the financial support provided by the UGC, New Delhi, under the Major Research Project Scheme No. F.39/737/2010 (SR).

References

Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Mahendra, M., Khanum, S. A., Singh, A. K., Shashikanth, S., Doreswamy, B. H., Sridhar, M. A. & Shashidhara Prasad, J. (2005). Acta Cryst. E61, o2990-o2991.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Naldoni, F. J., Claudino, A. L. R., Cruz, J. W., Chavasco, J. K., Faria e Silva, P. M., Veloso, M. P. & Dos Santos, M. H. (2009). J. Med. Food, 12, 403-407.
Naveen, S., Khanum, S. A., Devaiah, V. T., Shashikanth, S., Anandalwar, S. M. & Prasad, S. (2006). Anal. Sci. 22, 183-184.  [PubMed]
Selvi, A. T., Joseph, G. S. & Jayaprakasha, G. K. (2003). Food Microbiol. 20, 455-460.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]


Acta Cryst (2013). E69, o1676  [ doi:10.1107/S1600536813028444 ]

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