Acta Cryst. (2013). E69, o1759 [ doi:10.1107/S1600536813030389 ]
Abstract: In the title compound, C4H9Cl3N3O2P or CCl3C(O)NHP(O)(NHCH3)2, the P atom has a strongly distorted tetrahedral geometry due to the formation of intermolecular strong hydrogen bonds involving the N atoms. In the crystal, N-HO=P and N-HO=C hydrogen bonds connect the molecules into a two-dimensional array parallel to (100). An intramolecular PO contact [PO = 2.975 (3) Å] is observed. The CCl3 group is rotationally disordered, with occupancies of 0.60 (3) and 0.40 (3)
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