Received 10 September 2013
aChemistry, Institute of Natural and Mathematical Sciences, Massey University at Albany, PO Box 102904 North Shore Mail Centre, Auckland, New Zealand, and bInstitute of Fundamental Sciences - Chemistry, Massey University at Albany, PO Box 102904 North Shore Mail Centre, Auckland, New Zealand
Correspondence e-mail: email@example.com
The title adduct, [TiCl2(C23H30O2)(C13H10O]·0.5C13H10·C4H10O, is a monomer with a trigonal-bypyramidal coordination sphere of the TiIV atom in which the ligand O atoms of the bidentate diphenolate anion are located in both apical and equatorial positions. Chloride ligands occupy the remaining two equatorial sites of the trigonal bypyramid with the fluoren-9-ol O atom occupying the other apical site. The hydroxy group H atom of this latter group is hydrogen bonded to an O atom of a non-coordinating diethyl ether molecule. The title compound also contains a further fluorene solvent molecule, which lies across a centre of symmetry and which is equally disordered over an inversion centre.
For monomeric complexes of 4-coordinate titanium containing the 2,2'-methylene-bis-(4-methyl-6-tert-butylphenolato) ligand, see: Toscano et al. (1998). For two other structures with a five-coordinate metal atom containing this type of ligand, see: Okuda et al. (1995); Gielens et al. (1999).
Data collection: SMART (Siemens, 1995); cell refinement: SAINT (Siemens, 1995); data reduction: SAINT; program(s) used to solve structure: SHELXS90 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1999); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BV2226 ).
This work was supported by the award of a Massey University Research Fund Post-Doctoral Fellowship to CS. We are grateful to Ms T. Groutso of the University of Auckland for the data collection.
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