Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 12 (December 2013)


metal-organic compounds



bv2226 scheme

Acta Cryst. (2013). E69, m673-m674    [ doi:10.1107/S1600536813030249 ]

[6,6'-Bis(1,1-di­methyl­eth­yl)-4,4'-dimethyl-2,2'-methyl­enediphenolato-[kappa]2O,O']di­chlorido­(9H-fluoren-9-ol-[kappa]O)titanium(IV)-fluorene-diethyl ether (1/0.5/1)

A. J. Nielson, C. Shen and J. M. Waters

Abstract: The title adduct, [TiCl2(C23H30O2)(C13H10O]·0.5C13H10·C4H10O, is a monomer with a trigonal-bypyramidal coordination sphere of the TiIV atom in which the ligand O atoms of the bidentate diphenolate anion are located in both apical and equatorial positions. Chloride ligands occupy the remaining two equatorial sites of the trigonal bypyramid with the fluoren-9-ol O atom occupying the other apical site. The hy­droxy group H atom of this latter group is hydrogen bonded to an O atom of a non-coordinating diethyl ether mol­ecule. The title compound also contains a further fluorene solvent mol­ecule, which lies across a centre of symmetry and which is equally disordered over an inversion centre.


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