Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 12 (December 2013)


metal-organic compounds



cq2007 scheme

Acta Cryst. (2013). E69, m659-m660    [ doi:10.1107/S1600536813029450 ]

Chlorido([eta]6-N2-diphenylphosphanyl-N1,N1-diisopropyl-4-methoxybenz­amidine-[kappa]P)(triphenylphosphane-[kappa]P)ruthenium(II) trifluoromethansulfonate acetone disolvate

M. Kéchaou-Perrot, L. Vendier and A. Igau

Abstract: In the title compound, [RuCl(C18H15P)(C26H31N2OP)](CF3O3S)·2C3H6O, the RuII ion is coordinated in a three-legged piano stool, half-sandwich-type geometry by a chlorido ligand, a tri­phenyl­phosphine and a tethered [eta]6-(phenyl-p-O-meth­oxy) [kappa]1-P N-di­phenyl­phosphino N'-diisopropyl amidine ligand charge-balanced by a trifluormethansulfonate counter-anion. The [eta]6-coordination mode of the arene incorporated into the structure was generated in situ after addition of methyl tri­fluoro­methane­sulfonate to the neutral [eta]5-arene tethered precursor complex [RuCl(PPh3)([eta]5:[kappa]1-OC6H4C(NiPr2)=N-PPh2)] in di­chloro­methane solution.


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