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Volume 69 
Part 12 
Pages m629-m630  
December 2013  

Received 1 October 2013
Accepted 25 October 2013
Online 6 November 2013

Key indicators
Single-crystal X-ray study
T = 123 K
Mean [sigma](C-C) = 0.002 Å
R = 0.019
wR = 0.058
Data-to-parameter ratio = 18.2
Details
Open access

Di-[mu]2-acetato-1:2[kappa]2O:O';2:3[kappa]2O:O'-bis­{[mu]2-4,4'-di­chloro-2,2'-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2[kappa]6O,N,N',O':O,O';2:3[kappa]6O,O':O,N,N',O'-tri­cadmium

aDivision of Natural Sciences, Osaka Kyoiku University, Kashiwara, Osaka 582-8582, Japan, and bInstitute for Materials Chemistry and Engineering, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan
Correspondence e-mail: kubono@cc.osaka-kyoiku.ac.jp

In the title linear homo-trinuclear complex, [Cd3(C19H18Cl2N2O2)2(C2H3O2)2], the central CdII atom is located on a centre of inversion and has a distorted octa­hedral coordination geometry formed by four O atoms from two bidentate/tetra­dentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal CdII atom is square-pyramidal with the tetra­dentate part of the ligand in the basal plane and one O atom from an acetate ligand occupying the apical site. The six-membered CdN2C3 ring adopts a chair conformation. The acetate-bridged Cd...Cd distance is 3.3071 (2) Å. The crystal structure is stabilized by C-H...O hydrogen bonds, which form C(7) chain motifs and give rise to a two-dimensional supra­molecular network structure lying parallel to the ab plane.

Related literature

For metalloligands, see: Du et al. (2012[Du, D.-Y., Qin, J.-S., Sun, C.-X., Wang, X.-L., Zhang, S.-R., Shen, P., Li, S.-L., Su, Z.-M. & Lan, Y.-Q. (2012). J. Mater. Chem. 22, 19673-19678.]); Carlucci et al. (2011[Carlucci, L., Ciani, G., Proserpio, D. M. & Visconti, M. (2011). CrystEngComm, 13, 761-764.]); Das et al. (2011[Das, M. C., Xiang, S., Zhang, Z. & Chen, B. (2011). Angew. Chem. Int. Ed. 50, 10510-10520.]). Metal complexes with the Schiff base ligand, bis­(salicyl­idene)propane-1,3-di­amine can be metalloligands, forming linear homo- or hetero-trinuclear complexes with divalent metal salts, see: Atakol, Arici et al. (1999[Atakol, O., Arici, C., Ercan, F. & Ülkü, D. (1999). Acta Cryst. C55, 511-513.]), Das et al. (2013[Das, L. K., Biswas, A., Frontera, A. & Ghosh, A. (2013). Polyhedron, 52, 1416-1424.]); Fukuhara et al. (1990[Fukuhara, C., Tsuneyoshi, K., Matsumoto, N., Kida, S., Mikuriya, M. & Mori, M. (1990). J. Chem. Soc. Dalton Trans. pp. 3473-3479.]). For related structures, see: Atakol, Aksu et al. (1999[Atakol, O., Aksu, M., Ercan, F., Arici, C., Tahir, M. N. & Ülkü, D. (1999). Acta Cryst. C55, 1072-1075.]); Kubono et al. (2012[Kubono, K., Tani, K. & Yokoi, K. (2012). Acta Cryst. E68, m1430-m1431.]); Xue et al. (2012[Xue, L. W., Han, Y. J., Zhao, G. Q. & Feg, Y. X. (2012). Russ. J. Coord. Chem. 38, 24-28.]). For analysis of ring conformations, see: Cremer & Pople (1975[Cremer, D. & Pople, J. A. (1975). J. Am. Chem. Soc. 97, 1354-1358.]). For hydrogen-bond motifs, see: Bernstein et al. (1995[Bernstein, J., Davis, R. E., Shimoni, L. & Chang, N.-L. (1995). Angew. Chem. Int. Ed. 34, 1555-1573.]).

[Scheme 1]

Experimental

Crystal data
  • [Cd3(C19H18Cl2N2O2)2(C2H3O2)2]

  • Mr = 1209.83

  • Orthorhombic, P b c a

  • a = 19.3078 (15) Å

  • b = 11.2651 (8) Å

  • c = 20.535 (3) Å

  • V = 4466.5 (8) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.71 mm-1

  • T = 123 K

  • 0.21 × 0.16 × 0.11 mm

Data collection
  • Rigaku RAPID-HR diffractometer

  • Absorption correction: multi-scan (ABSCOR; Higashi, 1995[Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.727, Tmax = 0.828

  • 70676 measured reflections

  • 5107 independent reflections

  • 4990 reflections with I > 2[sigma](I)

  • Rint = 0.025

Refinement
  • R[F2 > 2[sigma](F2)] = 0.019

  • wR(F2) = 0.058

  • S = 1.00

  • 5107 reflections

  • 280 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.43 e Å-3

  • [Delta][rho]min = -0.84 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C15-H15...O3i 0.95 2.54 3.248 (2) 131
Symmetry code: (i) [-x+{\script{1\over 2}}, y+{\script{1\over 2}}, z].

Data collection: RAPID-AUTO (Rigaku, 2006[Rigaku (2006). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.]); cell refinement: RAPID-AUTO; data reduction: RAPID-AUTO; program(s) used to solve structure: SIR92 (Altomare, et al., 1993[Altomare, A., Cascarano, G., Giacovazzo, C. & Guagliardi, A. (1993). J. Appl. Cryst. 26, 343-350.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: PLATON (Spek, 2009)[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]; software used to prepare material for publication: CrystalStructure (Rigaku, 2010[Rigaku (2010). CrystalStructure. Rigaku Corporation, Tokyo, Japan.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CQ2008 ).


Acknowledgements

This study was supported financially in part by Grants-in-Aid for Scientific Research (No. 23550094) from the Japan Society for the Promotion of Science, and was performed under the Cooperative Research Program of "Network Joint Research Center for Materials and Devices".

References

Altomare, A., Cascarano, G., Giacovazzo, C. & Guagliardi, A. (1993). J. Appl. Cryst. 26, 343-350.  [CrossRef] [Web of Science] [IUCr Journals]
Atakol, O., Aksu, M., Ercan, F., Arici, C., Tahir, M. N. & Ülkü, D. (1999). Acta Cryst. C55, 1072-1075.  [CSD] [CrossRef] [IUCr Journals]
Atakol, O., Arici, C., Ercan, F. & Ülkü, D. (1999). Acta Cryst. C55, 511-513.  [CSD] [CrossRef] [IUCr Journals]
Bernstein, J., Davis, R. E., Shimoni, L. & Chang, N.-L. (1995). Angew. Chem. Int. Ed. 34, 1555-1573.  [CrossRef] [ChemPort] [Web of Science]
Carlucci, L., Ciani, G., Proserpio, D. M. & Visconti, M. (2011). CrystEngComm, 13, 761-764.  [Web of Science] [CSD] [CrossRef]
Cremer, D. & Pople, J. A. (1975). J. Am. Chem. Soc. 97, 1354-1358.  [CrossRef] [ChemPort] [Web of Science]
Das, L. K., Biswas, A., Frontera, A. & Ghosh, A. (2013). Polyhedron, 52, 1416-1424.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Das, M. C., Xiang, S., Zhang, Z. & Chen, B. (2011). Angew. Chem. Int. Ed. 50, 10510-10520.  [Web of Science] [CrossRef] [ChemPort]
Du, D.-Y., Qin, J.-S., Sun, C.-X., Wang, X.-L., Zhang, S.-R., Shen, P., Li, S.-L., Su, Z.-M. & Lan, Y.-Q. (2012). J. Mater. Chem. 22, 19673-19678.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Fukuhara, C., Tsuneyoshi, K., Matsumoto, N., Kida, S., Mikuriya, M. & Mori, M. (1990). J. Chem. Soc. Dalton Trans. pp. 3473-3479.  [CSD] [CrossRef]
Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.
Kubono, K., Tani, K. & Yokoi, K. (2012). Acta Cryst. E68, m1430-m1431.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Rigaku (2006). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.
Rigaku (2010). CrystalStructure. Rigaku Corporation, Tokyo, Japan.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Xue, L. W., Han, Y. J., Zhao, G. Q. & Feg, Y. X. (2012). Russ. J. Coord. Chem. 38, 24-28.  [CrossRef] [ChemPort]


Acta Cryst (2013). E69, m629-m630   [ doi:10.1107/S1600536813029413 ]

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