Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 12 (December 2013)


metal-organic compounds



gk2591 scheme

Acta Cryst. (2013). E69, m642    [ doi:10.1107/S1600536813029802 ]

N,N,N',N'-Tetra­methyl­ethylene­diammonium tetra­chlorido­zincate

M. Akhtar, M. Fettouhi, M. Ahmed, I. U. Khan and S. Ahmad

Abstract: The asymmetric unit of the title compound, (C6H18N2)[ZnCl4], consists of one tetra­chlorido­zincate anion and two half-N,N,N'N'-tetra­methyl­ethylenedi­ammonium cations. Each of the two di­ammonium cations is located about an inversion center and one of them is disordered over two sets of sites in a 0.780 (17):0.220 (17) ratio. The ZnII atom has a slightly distorted tetra­hedral coordination environment. The cations and anions are connected via N-H...Cl hydrogen bonds into chains extending along [0-11].


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