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Acta Cryst. (2013). E69, o1770-o1771
[ doi:10.1107/S1600536813029577 ]

(3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one

R. A. Nagalakshmi, J. Suresh, V. Jeyachandran, R. R. Kumar and P. L. N. Lakshman

Abstract: In the title compound, C18H14N2O5, the pyrrolidine ring adopts a shallow envelope conformation, with the C atom bearing the OH group (and remote from the N atom) displaced by 0.257 (2) Å from the other atoms. The cyclo­pentane ring has a twisted conformation about the C-C bond bearing one =O and one -OH grouping. The dihedral angle between the five-membered rings (all atoms) is 65.54 (9)° and the OH groups lie to the same side of the ring-junction. The mol­ecular structure features a weak intra­molecular O-H...O bond and a possible C-H...[pi] inter­action. In the crystal, the mol­ecules are linked into [010] chains by O-H...O hydrogen bonds. Weak C-H...O bonds connect the chains into (100) sheets.


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