Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 12 (December 2013)


metal-organic compounds



lh5666 scheme

Acta Cryst. (2013). E69, m664-m665    [ doi:10.1107/S1600536813030638 ]

Poly[[mu]3-aqua-aqua-[mu]5-(4-nitro­benzoato)-caesium]

G. Smith

Abstract: In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitro­benzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxyl­ate O,O'-chelate inter­action, a triple-bridging water mol­ecule and a monodentate water mol­ecule. A three-dimensional framework polymer is generated, within which there are water-carboxyl­ate O-H...O and water-water O-H...O hydrogen-bonding inter­actions.


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[ doi:10.1107/S1600536813030638/lh5666sup0.html ]
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[ doi:10.1107/S1600536813030638/lh5666Isup3.cml ]
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