Acta Cryst. (2013). E69, o1760 [ doi:10.1107/S1600536813030250 ]
Abstract: The title compound, C9H9N3O2S, is a monoclinic (C2/c) polymorph of the previously reported triclinic structure [Kang (2013). Acta Cryst. E69, o1327]. The molecule is almost planar with an r.m.s. deviation of 0.069 Å from the mean plane of all non-H atoms. The benzoyl and terminal thiourea fragments adopt a transoid conformation with respect to the central carbonyl O atom. Two intramolecular N-HO hydrogen bonds are present. In the crystal, N-HO and N-HS interactions link the molecules into zigzag chains extending along the c-axis direction.
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