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Volume 69 
Part 12 
Page m675  
December 2013  

Received 14 November 2013
Accepted 16 November 2013
Online 23 November 2013

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.010 Å
R = 0.039
wR = 0.076
Data-to-parameter ratio = 15.4
Details
Open access

Di-n-but­yl[4-hy­droxy-N'-(3-meth­oxy-2-oxido­benzyl­idene-[kappa]O2)benzo­hydrazidato-[kappa]2N,O]tin(IV)

aCollege of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China
Correspondence e-mail: qiaoyanling2004@163.com

In the title compound, [Sn(C4H9)2(C15H12N2O4)], the SnIV atom is coordinated by the N, O and O' atoms from the tridentate Schiff base dianion in an overall cis-C2SnNO2 trigonal-bipyramidal geometry. Adjacent mol­ecules are linked by O-H...O hydrogen bonds, forming a chain running along [001].

Related literature

For similar organotin compounds, see: Hong et al. (2013[Hong, M., Yin, H., Zhang, X., Li, C., Yue, C. & Cheng, S. (2013). J. Organomet. Chem. 724, 23-31.]).

[Scheme 1]

Experimental

Crystal data
  • [Sn(C4H9)2(C15H12N2O4)]

  • Mr = 517.18

  • Orthorhombic, I b a 2

  • a = 10.8504 (3) Å

  • b = 22.2977 (8) Å

  • c = 20.3988 (8) Å

  • V = 4935.2 (3) Å3

  • Z = 8

  • Mo K[alpha] radiation

  • [mu] = 1.06 mm-1

  • T = 293 K

  • 0.23 × 0.13 × 0.12 mm

Data collection
  • Bruker SMART 1000 diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.792, Tmax = 0.883

  • 16038 measured reflections

  • 4232 independent reflections

  • 3140 reflections with I > 2[sigma](I)

  • Rint = 0.061

Refinement
  • R[F2 > 2[sigma](F2)] = 0.039

  • wR(F2) = 0.076

  • S = 1.01

  • 4232 reflections

  • 275 parameters

  • 11 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 0.60 e Å-3

  • [Delta][rho]min = -0.47 e Å-3

  • Absolute structure: Flack (1983[Flack, H. D. (1983). Acta Cryst. A39, 876-881.]), 1986 Friedel pairs

  • Absolute structure parameter: -0.03 (3)

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O1-H1...O3i 0.82 2.11 2.840 (6) 148
O1-H1...O4i 0.82 2.26 2.923 (6) 139
Symmetry code: (i) [x, -y, z+{\script{1\over 2}}].

Data collection: SMART (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: NG5348 ).


Acknowledgements

We acknowledge the Students Science and Technology Innovation Fund of Liaocheng University (SF2013096).

References

Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Flack, H. D. (1983). Acta Cryst. A39, 876-881.  [CrossRef] [IUCr Journals]
Hong, M., Yin, H., Zhang, X., Li, C., Yue, C. & Cheng, S. (2013). J. Organomet. Chem. 724, 23-31.  [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]


Acta Cryst (2013). E69, m675  [ doi:10.1107/S1600536813031401 ]

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