Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 12 (December 2013)


metal-organic compounds



pk2502 scheme

Acta Cryst. (2013). E69, m651    [ doi:10.1107/S1600536813030432 ]

([mu]3-Hydrido)[[mu]3-2-(tri­methyl­sil­yl)ethyl­idyne-[kappa]3C1:C1:C1]tetra­kis­[([eta]5-cyclo­penta­dien­yl)cobalt(II)]

M. Haehnel, A. Spannenberg and U. Rosenthal

Abstract: In the title compound, [Co4(C5H5)4([mu]3-CCH2SiMe3)([mu]3-H)], the Co atoms form a distorted tetra­hedron with the ethyl­idyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co-Co bond lengths in the Co4 tetrahedron vary from 2.3844 (4) to 2.4608 (4) Å. Each Co atom is additionally [eta]5-bonded to a cyclopentadienyl (Cp) anion.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813030432/pk2502sup0.html ]
Supplementary materials


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster