Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 12 (December 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m635-m636    [ doi:10.1107/S1600536813029656 ]

Di-[mu]-oxido-bis­({2,2'-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphen­olato}titanium(IV)) chloro­form disolvate

K. V. Zaitsev, S. S. Karlov, Y. A. Piskun, I. V. Vasilenko and A. V. Churakov

Abstract: In the title structure, [Ti2(C16H16N2O2)2O2]·2CHCl3, the Ti atom is coordinated in a distorted octa­hedral geometry by the O,N,N',O' donor set of the salalen ligand and by two [mu]2-oxide O atoms, which bridge two Ti(salalen) fragments into a centrosymmetric dimeric unit. In the central Ti2([mu]2-O)2 fragment, the metal-oxygen distances are significantly different [1.7962 (19) and 1.9292 (19) Å]. In the crystal, the chloro­form mol­ecule is anchored via an N-H...Cl and a bifurcated C-H...(O,O) hydrogen bond. Slipped [pi]-[pi] stacking [shortest C...C distance = 3.585 (4) Å] and C-H...[pi] inter­actions contribute to the coherence of the structure.

CCDC reference: 969061

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (71.4 kbytes)
[ doi:10.1107/S1600536813029656/qk2062sup0.html ]
Supplementary materials

moldisplay filedownload file

MDL mol file (8.1 kbytes)
[ doi:10.1107/S1600536813029656/qk2062Isup3.mol ]
Supplementary material


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster