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Volume 69 
Part 12 
Pages m647-m648  
December 2013  

Received 9 October 2013
Accepted 2 November 2013
Online 9 November 2013

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.010 Å
R = 0.060
wR = 0.141
Data-to-parameter ratio = 14.3
Details
Open access

Poly[[([mu]2-4,4'-bipyridyl-[kappa]2N:N')bis­{[mu]2-N-[2-(2-hy­droxy­benzo­yl)carbamo­thio­yl]acetamidato-[kappa]4O,N,O':S}bis­(nitrato-[kappa]2O,O')dicadmium] di­methyl­formamide tetra­solvate]

aZhicheng College, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China
Correspondence e-mail: yyomh@163.com

The asymmetric unit of the title complex, {[Cd2(C10H10N3O3S)2(C10H8N2)(NO3)2]·4C3H7NO}n, consists of one CdII cation, one N-[2-(2-hy­droxy­benzo­yl)carbamo­thio­yl]acetamidate ligand, half a 4,4'-bipyridyl ligand, one coordinating nitrate anion and two di­methyl­formamide solvent mol­ecules of crystallization. The bipyridine ligand is completed by inversion symmetry. The metal cation exhibits a distorted penta­gonal-bipyramidal coordination geometry provided by two O and one N atoms of the thio­semicarbazide ligand, two O atoms of the nitrate anion, one S atom of a neighbouring thio­semicarbazide ligand and one 4,4'-bi­pyridine N atom. The bridging role of the thio­semicarbazide ligand through the S atom leads to centrosymmetric binuclear units, which are further linked by 4,4'-bi­pyridine units, forming polymeric chains extending along the b-axis direction. An intra­molecular N-H...O hydrogen bond occurs. The crystal structure also features N-H...O and O-H...O hydrogen bonds, leading to the formation of a three-dimensional network.

Related literature

For background to the properties and applications of thio­semicarbazone complexes, see: Quiroga & Ranninger (2004[Quiroga, A. G. & Ranninger, C. N. (2004). Coord. Chem. Rev. 248, 119-133.]); Kasuga et al. (2003[Kasuga, N. C., Sekino, K., Ishikawa, M., Honda, A., Yokoyama, M., Nakano, S., Shimada, N., Koumo, C. & Nomiya, K. (2003). J. Inorg. Biochem. 96, 298-310.]); Floquet et al. (2009[Floquet, S., Muñoz, M. C., Guillot, R., Riviére, E., Blain, G., Réal, J.-A. & Boillot, M.-L. (2009). Inorg. Chim. Acta, 362, 56-64.]); Hassanien et al. (2008[Hassanien, M. M., Gabr, I. M., Abdel-Rhman, M. H. & El-Asmy, A. A. (2008). Spectrochim. Acta Part A, 71, 73-79.]); Latheef et al. (2006[Latheef, L., Manoj, E. & Prathapachandra Kurup, M. R. (2006). Acta Cryst. C62, o16-o18.]); Babb et al. (2003[Babb, J. E. V., Burrows, A. D., Harrington, R. W. & Mahon, M. F. (2003). Polyhedron, 22, 673-686.]). For related structures, see: Ke et al. (2007[Ke, Y.-Z., Zheng, L.-F., Luo, J.-H., Huang, X.-H. & Huang, C.-C. (2007). Acta Cryst. C63, m343-m345.]); Wang et al. (2010[Wang, Y.-B., Pan, T.-H., Liang, Q., Liu, D.-S. & Huang, C.-C. (2010). Acta Cryst. C66, m127-m129.]); Liu et al. (2013[Liu, J.-J., Liao, J.-Z., Li, Z.-Y., Wang, Y. & Huang, C.-C. (2013). Acta Cryst. C69, 613-615.]). For the synthesis of the N-(2-(2-hy­droxy­benzo­yl)carbamo­thio­yl)acetamide ligand, see: Wang et al. (2000[Wang, X., Li, Z., Da, Y. & Chen, J. (2000). Synth. Commun. 30, 3405-3414.]).

[Scheme 1]

Experimental

Crystal data
  • [Cd2(C10H10N3O3S)2(C10H8N2)(NO3)2]·4C3H7NO

  • Mr = 1301.93

  • Monoclinic, P 21 /n

  • a = 13.831 (3) Å

  • b = 15.280 (3) Å

  • c = 14.363 (3) Å

  • [beta] = 110.55 (3)°

  • V = 2842.4 (12) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.90 mm-1

  • T = 293 K

  • 0.30 × 0.18 × 0.08 mm

Data collection
  • Rigaku Saturn 724+ CCD diffractometer

  • Absorption correction: numerical (CrystalClear; Rigaku, 2007[Rigaku (2007). CrystalClear. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.813, Tmax = 0.946

  • 18197 measured reflections

  • 4980 independent reflections

  • 4753 reflections with I > 2[sigma](I)

  • Rint = 0.043

Refinement
  • R[F2 > 2[sigma](F2)] = 0.060

  • wR(F2) = 0.141

  • S = 1.28

  • 4980 reflections

  • 349 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.70 e Å-3

  • [Delta][rho]min = -0.63 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
N1-H1...O7i 0.86 2.01 2.871 (6) 174
N3-H3...O6 0.86 1.96 2.619 (6) 133
O6-H6...O8ii 0.82 1.70 2.502 (9) 164
Symmetry codes: (i) -x+2, -y, -z+1; (ii) [x+{\script{1\over 2}}, -y+{\script{1\over 2}}, z+{\script{1\over 2}}].

Data collection: CrystalClear (Rigaku, 2007[Rigaku (2007). CrystalClear. Rigaku Corporation, Tokyo, Japan.]); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXL97.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: RZ5087 ).


Acknowledgements

This work was supported by the National Training Programs of Innovation and Entrepreneurship for Undergraduates (grant No. 201313470010).

References

Babb, J. E. V., Burrows, A. D., Harrington, R. W. & Mahon, M. F. (2003). Polyhedron, 22, 673-686.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Floquet, S., Muñoz, M. C., Guillot, R., Riviére, E., Blain, G., Réal, J.-A. & Boillot, M.-L. (2009). Inorg. Chim. Acta, 362, 56-64.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Hassanien, M. M., Gabr, I. M., Abdel-Rhman, M. H. & El-Asmy, A. A. (2008). Spectrochim. Acta Part A, 71, 73-79.  [ChemPort]
Kasuga, N. C., Sekino, K., Ishikawa, M., Honda, A., Yokoyama, M., Nakano, S., Shimada, N., Koumo, C. & Nomiya, K. (2003). J. Inorg. Biochem. 96, 298-310.  [Web of Science] [CSD] [CrossRef] [PubMed] [ChemPort]
Ke, Y.-Z., Zheng, L.-F., Luo, J.-H., Huang, X.-H. & Huang, C.-C. (2007). Acta Cryst. C63, m343-m345.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Latheef, L., Manoj, E. & Prathapachandra Kurup, M. R. (2006). Acta Cryst. C62, o16-o18.  [CSD] [CrossRef] [IUCr Journals]
Liu, J.-J., Liao, J.-Z., Li, Z.-Y., Wang, Y. & Huang, C.-C. (2013). Acta Cryst. C69, 613-615.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Quiroga, A. G. & Ranninger, C. N. (2004). Coord. Chem. Rev. 248, 119-133.  [Web of Science] [CrossRef] [ChemPort]
Rigaku (2007). CrystalClear. Rigaku Corporation, Tokyo, Japan.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Wang, X., Li, Z., Da, Y. & Chen, J. (2000). Synth. Commun. 30, 3405-3414.  [Web of Science] [CrossRef] [ChemPort]
Wang, Y.-B., Pan, T.-H., Liang, Q., Liu, D.-S. & Huang, C.-C. (2010). Acta Cryst. C66, m127-m129.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]


Acta Cryst (2013). E69, m647-m648   [ doi:10.1107/S1600536813030055 ]

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