Acta Cryst. (2013). E69, m666 [ doi:10.1107/S1600536813030900 ]
Abstract: The asymmetric unit of the title compound, (C6H20N3)[BiCl6]·H2O, consists of a triprotonated bis(3-azaniumylpropyl)azanium cation, two halves of an octahedral [BiCl6]3- anion, each of the BiIII atoms lying on an inversion centre, and a water molecule. In the crystal, the anions and water molecules are linked by O-HCl hydrogen bonds, forming chains running parallel to [0-11]. The anionic chains and the cations are further linked into a three-dimensional network by N-HCl and N-HO hydrogen-bond interactions.
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