Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 12 (December 2013)


organic compounds



tk5273 scheme

Acta Cryst. (2013). E69, o1818    [ doi:10.1107/S1600536813031656 ]

2-Meth­oxy-3-(tri­methyl­sil­yl)phenyl­boronic acid

K. Durka, S. Lulinski and J. Serwatowski

Abstract: The mol­ecular structure of the title compound, C10H17BO3Si, features an intra­molecular O-H...O hydrogen bond; the boronic group group has an exo-endo conformation. In the crystal, the mol­ecules inter­act with each other by O-H...O hydrogen bonds, producing centrosymmetric dimers that are linked by weak [pi]-[pi] stacking inter­actions featuring specific short B...C contacts [e.g. 3.372 (2) Å], forming an infinite columnar structure aligned along the a-axis direction.


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