Received 12 November 2013
The molecular structure of the title compound, C10H17BO3Si, features an intramolecular O-HO hydrogen bond; the boronic group group has an exo-endo conformation. In the crystal, the molecules interact with each other by O-HO hydrogen bonds, producing centrosymmetric dimers that are linked by weak - stacking interactions featuring specific short BC contacts [e.g. 3.372 (2) Å], forming an infinite columnar structure aligned along the a-axis direction.
For structures of related ortho-alkoxy arylboronic acids, see: Cyranski et al. (2012). For binding energies of other boronic acid dimers, see: Cyranski et al. (2008); Durka et al. (2012). For the PIXEL program, see Gavezzotti (2003). For the synthesis, see: Durka et al. (2010).
Data collection: APEX2 (Bruker, 2010); cell refinement: SAINT (Bruker, 2010); data reduction: SAINT and SORTAV (Blessing, 1995); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2005); software used to prepare material for publication: PLATON (Spek, 2009).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: TK5273 ).
The X-ray measurements were undertaken in the Crystallographic Unit of the Physical Chemistry Laboratory at the Chemistry Department of the University of Warsaw. This work was supported by the Warsaw University of Technology. The support by Aldrich Chemical Co., Milwaukee, WI, USA, through continuous donation of chemicals and equipment is gratefully acknowledged.
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