Acta Cryst. (2013). E69, o1739-o1740 [ doi:10.1107/S1600536813029565 ]
Abstract: In the title compound, C24H40N4S34+·2SiF62-·3CH3OH, the central tertiary amine function is protonated and is connected to three thiophen-2-ylmethylamino-n-propyl groups, forming the arms of a T-shaped cation that has two pockets. Each arm contains one protonated secondary amine function, and each pocket is occupied by one SiF62- anion bonded via two N-HF interactions with the protonated amine group on the middle arm, while two methanol solvent molecules are N-HO hydrogen-bonded with the other secondary protonated amine groups on the side arms. Weak O-HO and O-HF hydrogen bonds between the solvent molecules and between the solvent molecules and the anions, respectively, are also observed. All three thiophene groups in the arms are disordered over two sets of sites, with occupancy ratios of 0.828 (3):0.172 (3), 0.910 (2):0.090 (2) and 0.890 (3):0.110 (3).
CCDC reference: 968755
Hyper-Text Markup Language (HTML) file (153.2 kbytes)
To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.
The download button will force most browsers to prompt for a file name to store the data on your hard disk.
Where possible, images are represented by thumbnails.
Copyright © International Union of Crystallography