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Volume 69 
Part 12 
Page m682  
December 2013  

Received 14 November 2013
Accepted 21 November 2013
Online 27 November 2013

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.004 Å
R = 0.036
wR = 0.092
Data-to-parameter ratio = 32.4
Details
Open access

Bis[[mu]-N-(pyridin-2-yl)methane­sulfon­amido-[kappa]2N:N']silver(I)

aDepartment of Hospitality Management, Taoyuan Innovation Institute of Technology, Jhongli 32091, Taiwan, and bDepartment of Chemistry, Chung-Yuan Christian University, Jhongli 32023, Taiwan
Correspondence e-mail: cwyeh@cycu.org.tw

In the title compound, [Ag2(C6H7N2O2S)2], the AgI atom is coordinated by two N atoms from two N-(pyridin-2-yl)methane­sulfonamidate anions in a slightly bent linear geometry [N-Ag-N = 166.03 (7)°]. The AgI atoms are bridged by the N-(pyridin-2-yl)methane­sulfonamidate anions, forming a centrosymmetric dinuclear mol­ecule, in which the Ag...Ag distance is 2.7072 (4) Å.

Related literature

For related di(pyrid­yl/pyrimid­yl)amide structures, see: Hu et al. (2004[Hu, H.-L., Yeh, C.-W. & Chen, J.-D. (2004). Eur. J. Inorg. Chem. pp. 4696-4701.]); Hsu et al. (2008[Hsu, Y.-F., Lin, C.-H., Chen, J.-D. & Wang, J.-C. (2008). Cryst. Growth Des. 8, 1094-1096.]); Yeh et al. (2008[Yeh, C.-W., Chen, J.-D. & Wang, J.-C. (2008). Polyhedron, 27, 3611-3618.]); Tsai et al. (2010[Tsai, T.-P., Huang, Y.-T., Ray, U., Chang, Y.-J., Cheng, P.-C., Wu, C.-J., Chen, J.-D. & Wang, J.-C. (2010). Polyhedron, 29, 3081-3088.]). For related methyl-4-(pyridin-pyrimidin-2-ylcarbamo­yl)benz­o­ate structures, see: Wu et al. (2011[Wu, C.-J., Sie, M.-J., Hsiao, H.-L. & Chen, J.-D. (2011). CrystEngComm, 13, 4121-4130.]); Hsiao et al. (2012[Hsiao, H.-L., Wu, C.-J., Hsu, W., Yeh, C.-W., Xie, M.-Y., Huang, W.-J. & Chen, J.-D. (2012). CrystEngComm, 14, 8143-8152.]). For related phosphinic amide structures, see: Yeh & Chen (2011[Yeh, C.-W. & Chen, J.-D. (2011). Inorg. Chem. Commun. 14, 1212-1216.]); Yeh et al. (2012[Yeh, C.-W., Chang, K.-H., Hu, C.-Y., Hsu, W. & Chen, J.-D. (2012). Polyhedron, 31, 657-664.]).

[Scheme 1]

Experimental

Crystal data
  • [Ag2(C6H7N2O2S)2]

  • Mr = 558.13

  • Monoclinic, P 21 /c

  • a = 6.4406 (2) Å

  • b = 15.4580 (5) Å

  • c = 8.0789 (2) Å

  • [beta] = 97.143 (2)°

  • V = 798.08 (4) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 2.74 mm-1

  • T = 296 K

  • 0.20 × 0.10 × 0.10 mm

Data collection
  • Bruker APEXII CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2000[Bruker (2000). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.636, Tmax = 0.747

  • 12917 measured reflections

  • 3569 independent reflections

  • 2732 reflections with I > 2[sigma](I)

  • Rint = 0.048

Refinement
  • R[F2 > 2[sigma](F2)] = 0.036

  • wR(F2) = 0.092

  • S = 1.05

  • 3569 reflections

  • 110 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 1.32 e Å-3

  • [Delta][rho]min = -1.22 e Å-3

Table 1
Selected bond lengths (Å)

Ag-N1 2.1373 (19)
Ag-N2i 2.1654 (19)
Symmetry code: (i) -x, -y+1, -z+1.

Data collection: APEX2 (Bruker, 2010[Bruker (2010). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2010[Bruker (2010). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: DIAMOND (Brandenburg, 1999[Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: SHELXL97.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5753 ).


Acknowledgements

We are grateful to the Taoyuan Innovation Institute of Technology and the National Science Council of Taiwan for support.

References

Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Bruker (2000). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2010). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Hsiao, H.-L., Wu, C.-J., Hsu, W., Yeh, C.-W., Xie, M.-Y., Huang, W.-J. & Chen, J.-D. (2012). CrystEngComm, 14, 8143-8152.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Hsu, Y.-F., Lin, C.-H., Chen, J.-D. & Wang, J.-C. (2008). Cryst. Growth Des. 8, 1094-1096.  [CSD] [CrossRef] [ChemPort]
Hu, H.-L., Yeh, C.-W. & Chen, J.-D. (2004). Eur. J. Inorg. Chem. pp. 4696-4701.  [Web of Science] [CSD] [CrossRef]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Tsai, T.-P., Huang, Y.-T., Ray, U., Chang, Y.-J., Cheng, P.-C., Wu, C.-J., Chen, J.-D. & Wang, J.-C. (2010). Polyhedron, 29, 3081-3088.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Wu, C.-J., Sie, M.-J., Hsiao, H.-L. & Chen, J.-D. (2011). CrystEngComm, 13, 4121-4130.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Yeh, C.-W., Chang, K.-H., Hu, C.-Y., Hsu, W. & Chen, J.-D. (2012). Polyhedron, 31, 657-664.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Yeh, C.-W. & Chen, J.-D. (2011). Inorg. Chem. Commun. 14, 1212-1216.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Yeh, C.-W., Chen, J.-D. & Wang, J.-C. (2008). Polyhedron, 27, 3611-3618.  [Web of Science] [CSD] [CrossRef] [ChemPort]


Acta Cryst (2013). E69, m682  [ doi:10.1107/S1600536813031814 ]

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