Acta Cryst. (2013). E69, o1732-o1733 [ doi:10.1107/S1600536813028857 ]
Abstract: The asymmetric unit of the title compound, C8H3BrN2, consists of two molecules. The crystal structure features undulating molecular sheets with the molecules linked by C-HN hydrogen bonds with one N atom acting as a bifurcated acceptor. NBr interactions also occur [NBr = 2.991 (3) and 3.099 (3) Å]. Interlayer association is accomplished by offset face-to-face arene interactions [centroid-centroid distance = 3.768 (4) Å].
CCDC reference: 967566
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