Acta Cryst. (2014). E70, i5 [ doi:10.1107/S1600536813034089 ]
Abstract: The structure of the title compound is characterized by the presence of two different anions, (PO4)3- and (P2O7)4- with an eclipsed conformation. The crystal structure consists of edge-sharing [NiO6] octahedra forming an [Ni3O14] chain running parallel to . Adjacent chains are connected through edges and apices to PO4 and P2O7 groups in such a way as to build a three-dimensional host lattice. The resulting framework presents intersecting tunnels running along  and  in which the 11-coordinated potassium cation is located. The crystal structure of this new phosphate probably represents a new structural type.
CCDC reference: 977736
Hyper-Text Markup Language (HTML) file (67.2 kbytes)
To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.
The download button will force most browsers to prompt for a file name to store the data on your hard disk.
Where possible, images are represented by thumbnails.
Copyright © International Union of Crystallography