Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)

organic compounds

fj2652 scheme

Acta Cryst. (2014). E70, o61    [ doi:10.1107/S1600536813033230 ]

Hexa­kis­(3-chloro-2-methyl­anilinium) cyclo­hexa­phosphate dihydrate

R. Bel Haj Salah, L. Khederi and M. Rzaigui

Abstract: In the organic/inorganic salt hydrate, 6C7H9ClN+·P6O186-·2H2O, the cyclo­hexa­phosphate anion resides on an inversion centre. The asymmetric unit consists of three cations, one half-anion and a water mol­ecule. In the crystal, the water mol­ecules and the [P6O18]6- anions are linked by O-H...O hydrogen bonds, generating infinite layers parallel to the ab plane. These layers are inter­connected by the organic cations through N-H...O hydrogen bonds.

CCDC reference: 975722

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