Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)

metal-organic compounds

gg2131 scheme

Acta Cryst. (2014). E70, m24    [ doi:10.1107/S1600536813032832 ]


L. Liao, C. W. Ingram, J. Bacsa and C. Parker

Abstract: The title compound, [Co(C24H28N2O6)]n, crystallizes as infinite chains related to one another by inversion centers, giving a centrosymmetric coordination polymer. The CoII ion, situated on a twofold rotation axis, forms a complex with the crown-4 moiety of the 3,3'-[(1,7-dioxa-4,10-di­aza­cyclo­do­decane-4,10-di­yl)bis­(meth­ylene)]dibenzoate anion. The dis­torted octahedral coordination sphere of the CoII ion is completed by two carboxyl­ate O atoms from two bridging intra-chain ligands. Metallomacrocyclic rings of 16 atoms are present, with each ring containing two CoII ions and 14 atoms from the bridging ligands. These units repeat as infinite zigzag chains along [101].

CCDC reference: 975042

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (66.9 kbytes)
[ doi:10.1107/S1600536813032832/gg2131sup0.html ]
Supplementary materials

cdxdisplay filedownload file

Chemdraw file (8.8 kbytes)
[ doi:10.1107/S1600536813032832/gg2131Isup3.cdx ]
Supplementary material


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster