Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)


metal-organic compounds



is5307 scheme

Acta Cryst. (2014). E70, m3    [ doi:10.1107/S1600536813031887 ]

Poly[bis­([mu]4-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-[kappa]4O1:O1':O4:O4')bis­(tetra­hydro­furan-[kappa]O)dizinc]

S. B. Choi, Y. H. Jhon, N. Ko and J. K. Yang

Abstract: The title compound, [Zn2(C8F4O4)2(C4H8O)2]n, has a three-dimensional metal-organic framework structure. The asymmetric unit consists of two ZnII atoms, two tetrahydrofuran ligands, one 2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ate ligand and two half 2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ate ligands, which are completed by inversion symmetry. One ZnII atom has a distorted trigonal-bipyramidal coordination geometry, while the other has a distorted octa­hedral geometry. Two independent tetra­hydro­furan ligands are each disordered over two sets of sites with occupancy ratios of 0.48 (4):0.52 (4) and 0.469 (17):0.531 (17).


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