Acta Cryst. (2014). E70, m18-m19 [ doi:10.1107/S1600536813032169 ]
Abstract: In the title complex, [Ni(C6H9N2O3S)2(H2O)2]·2H2O, the NiII atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazolesulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octahedral configuration. The crystal structure displays O-HO and N-HO hydrogen bonds, which connect the components into an extended three-dimensional network.
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