Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)


metal-organic compounds



jj2177 scheme

Acta Cryst. (2014). E70, m18-m19    [ doi:10.1107/S1600536813032169 ]

Di­aqua­bis­(2-ethyl-5-methyl­imidazole-4-sulfonato-[kappa]2N3,O)nickel(II) dihydrate

A. P. Purdy and R. J. Butcher

Abstract: In the title complex, [Ni(C6H9N2O3S)2(H2O)2]·2H2O, the NiII atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazole­sulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octa­hedral configuration. The crystal structure displays O-H...O and N-H...O hydrogen bonds, which connect the components into an extended three-dimensional network.


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