Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)


organic compounds



lh5671 scheme

Acta Cryst. (2014). E70, o68-o69    [ doi:10.1107/S1600536813033540 ]

Ethyl 2-[2-(2,4-diphenyl-3-aza­bicyclo­[3.3.1]nonan-9-yl­idene)hydrazin-1-yl]-4-methyl-1,3-thia­zole-5-carboxyl­ate di­methyl­formamide monosolvate

S. Jothivel and S. Kabilan

Abstract: In the title mol­ecule, C27H30N4O2S·C3H7NO, the fused piperidine and cyclo­hexane rings adopt a twin chair conformation and the phenyl groups occupy equatorial sites. The phenyl rings make a dihedral angle of 40.74 (2)°. In the crystal, the di­methyl­formamide solvent mol­ecule is connected to the main mol­ecule by an N-H...O hydrogen bond. An additional N-H...O hydrogen bond connects mol­ecules into chains along [100]. Pairs of weak C-H...O hydrogen bonds connect inversion-related chains. The ethyl group was refined as disordered over two sets of sites with an occupancy ratio of 0.660 (17):0.340 (17).


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813033540/lh5671sup0.html ]
Supplementary materials


cdxdisplay filedownload file

Chemdraw file (1234.4 kbytes)
[ doi:10.1107/S1600536813033540/lh5671Isup3.cdx ]
Supplementary material


cmldisplay filedownload file

Chemical Markup Language (CML) file (11.2 kbytes)
[ doi:10.1107/S1600536813033540/lh5671Isup4.cml ]
Supplementary material


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster