Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)


metal-organic compounds



mw2118 scheme

Acta Cryst. (2014). E70, m11-m12    [ doi:10.1107/S160053681303256X ]

An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)

A. Hamala, C. Fritz, G. Rawji and V. Lynch

Abstract: In the title complex, [PtCl2(C12H6N2O2)]·CH3CN, the PtII atom lies in a slightly distorted square-planar arrangement defined by an N2Cl2 donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally displaced with respect to each other. This prevents any overlap of the phenanthroline rings and thus there is no possibility of any [pi]-[pi] inter­actions between aromatic rings.


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