Acta Cryst. (2014). E70, m16 [ doi:10.1107/S1600536813033072 ]
Abstract: The title dinuclear half-sandwich complex, [CpTi(OCH=CH2)(2-N-iPr)]2 (Cp = cyclopentadienyl; iPr = isopropyl), was obtained from the reaction of Cp2TiCl2, n-butyllithium and isopropylamine in tetrahydrofuran. Each TiIV atom is coordinated by one Cp ligand, one vinyloxy unit and two bridging imido groups in a strongly distorted tetrahedral geometry. There are two half molecules in the asymmetric unit, such that whole molecules being generated by inversion symmetry.
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