Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)


metal-organic compounds



pk2508 scheme

Acta Cryst. (2014). E70, m16    [ doi:10.1107/S1600536813033072 ]

Bis([mu]2-iso­propyl­imido-[kappa]2N:N)bis­[([eta]5-cyclo­penta­dien­yl)(ethenolato-[kappa]O)titanium(IV)]

M. Haehnel, A. Spannenberg and U. Rosenthal

Abstract: The title dinuclear half-sandwich complex, [CpTi(OCH=CH2)([mu]2-N-iPr)]2 (Cp = cyclo­penta­dien­yl; iPr = isopropyl), was ob­tained from the reaction of Cp2TiCl2, n-butyl­lithium and iso­propyl­amine in tetra­hydro­furan. Each TiIV atom is coordinated by one Cp ligand, one vin­yloxy unit and two bridging imido groups in a strongly distorted tetra­hedral geometry. There are two half mol­ecules in the asymmetric unit, such that whole mol­ecules being generated by inversion symmetry.


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