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Acta Cryst. (2014). E70, o72  [ doi:10.1107/S1600536813033734 ]

N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate-1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)

Y. Q. Chang, Y. Zhang and H. L. Lian

Abstract: In the title compound, 2C11H18N+·2PF6-·C12H24O6, the 18-crown-6 mol­ecule has crystallographically imposed inversion symmetry. In the crystal, it inter­acts with the cation through weak C-H...O hydrogen bonds. The cations and anions are further linked via N-H...F and C-H...F hydrogen bonds, leading to a sandwich structure .


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