Received 26 November 2013
The title compound, [Bi(C4H8NOS2)2I(C12H8N2)], is monomeric, with the BiIII atom chelated by the two S atoms of two morpholine-4-carbodithioate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate BiIII atom adopting a highly distorted monocapped octahedral geometry.
For dithiocarbamates as ligands to transition metals, see: Xu et al. (2001); Bardaji et al. (1994). For bismuth(III)-dithiocarbamate complexes, see: Yin et al. (2003). For related Bi/N structures, see: Baraanyi et al. (1977).
Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SJ5375 ).
We acknowledge financial support from the Luliang University Campus Youth Foundation.
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