Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)


metal-organic compounds



sj5375 scheme

Acta Cryst. (2014). E70, m20    [ doi:10.1107/S1600536813033515 ]

Iodido­bis­(morpholine-4-carbodi­thio­ato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')bis­muth(III)

F. Li, H. Yin and G. Wu

Abstract: The title compound, [Bi(C4H8NOS2)2I(C12H8N2)], is monomeric, with the BiIII atom chelated by the two S atoms of two morpholine-4-carbodi­thio­ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate BiIII atom adopting a highly distorted monocapped octa­hedral geometry.


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